Our article on nickel-catalyzed cross-couplings via C–N bond activation is featured in the JACS Young Investigators Virtual Issue! Congratulations to the team, Corey Basch, Jennie Liao, Jianyu Xu, and Jake Piane! Read more on UDaily.
Monthly Archives: August 2017
Undergraduate Research and Service Celebratory Symposium
New Method for Quat Center Formation
Congratulations to Kelsey Cobb, Javon Rabb-Lynch, Megan Hoerrner, Alex Manders, and Qi Zhou on their recent development of a stereospecific Suzuki–Miyaura cross-coupling of allylic pivalates to set all-carbon quaternary stereocenters (http://pubs.acs.org/doi/full/10.1021/acs.orglett.7b02063)! This reaction is enabled by a simple nickel/BISBI catalyst system, and enables efficient formation of allylic products with internal alkenes.