Publications

(72) “Fluoride Capture as a Strategy for Solubilizing Porous Coordination Cages” Antonio, A. M.; Dworzak, M. R.; Yap, G. P. A.; Bloch, E. D. Submitted.

(71) “Elaboration of Porous Salts” Gosselin, A. J.; Antonio, A. M.; Korman, K. J.; Deegan, M. M.; Yap, G. P. A.; Bloch, E. D. J. Am. Chem. Soc. 2021, 143, 14956-14961.

(70) “Facile and Rapid Room-Temperature Electrosynthesis and Controlled Surface Growth of Fe-MIL-101 and Fe-MIL-101-NH2” Wu, W.; Decker, G. E.; Weaver, A. E.; Arnoff, A. I.; Bloch, E. D.; Rosenthal, J. ACS Cent. Sci. 2021, 7, 1427-1433.

(69) “Tuning Water Adsorption, Stability, and Phase in Fe-MIL-101 and Fe-MIL-88 Analogs with Amide Functionalization” Kuznicki, A.; Lorzing, G. R.; Bloch, E. D. Chem. Commun. 2021, 57, 8312-8315.

(68) “Using Helium Pycnometry to Study the Apparent Densities of Metal-Organic Frameworks” Decker, G. E.; Bloch, E. D. ACS Appl. Mater. Interfaces 2021, Article ASAP. DOI: 10.1021/acsami.1c07304

(67) “Stabilizing Porosity in Organic Cages Through Coordination Chemistry” Deegan, M. M.; Bhattacharjee, R,; Caratzoulas, S.; Bloch, E. D. Inorg. Chem. 2021, 60, 7044-7050.

(66) “Synthesis and Characterization of an Isoreticular Family of Calixarene-Capped Porous Coordination Cages” Dworzak, M. R.; Deegan, M. M.; Yap, G. P. A.; Bloch, E. D. Inorg. Chem. 2021, 60, 5607-5616.

(65) “Synthesis, Characterization, and Polymerization of Capped Paddlewheel Porous Cages” Deegan, M. M.; Bloch, E. D. Dalton Trans. 202150, 3127-3131.

(64) “Gas Storage in Porous Molecular Materials” Deegan, M. M.; Dworzak, M. R.; Gosselin, A. J.; Korman, K. J.; Bloch, E. D. Chem. Eur. J. 2021, 27, 4531-4547. Invited Contribution.

(63) “Manipulating Solvent and Solubility in the Synthesis, Activation, and Modification of Permanently Porous Coordination Cages” Deegan, M. M.; Antonio, A. M.;  Taggart, G. A.; Bloch, E. D. Coord. Chem. Rev. 2021, 430, 213679. Invited Contribution.

(62) “Porous Metal-Organic Alloys Based on Soluble Coordination Cages” Antonio, A. M.; Korman, K. J. Yap, G. P. A.; Bloch, E. D. Chem. Sci. 202011, 12540-12546.

(61) “Elucidating the Structure of the Metal-Organic Framework Ru-HKUST-1” Lorzing, G. R.; Balto, K. P.; Antonio, A. M.; Trump, B. A.; Brown, C. M.; Bloch, E. D. Chem. Mater. 2020, 32, 7710-7715.

(60) “Using Low-Pressure Methane Adsorption Isotherms for Higher-Throughput Screening of Methane Storage Materials” Korman, K, J.; Decker, G. E.; Deegan, M. M.; Dworzak, M. R.; Antonio, A. M.; Taggart, G. A.; Bloch, E. D. ACS Appl. Mater. Interfaces 2020, 12, 40318-40327.

(59) “Evaluating UiO-66 Metal-Organic Framework (MOF) Nanoparticles as Acid-Sensitive Carriers for Pulmonary Drug Delivery Applications” Jarai, B. M.; Stillman, Z.; Attia, L.; Decker, G. E.; Bloch, E. D.; Fromen, C. A. ACS Appl. Mater. Interfaces 2020, 12, 38989-39004.

(58) “Design and Synthesis of Aryl-Functionalized Carbazole-Based Porous Coordination Cages” Rowland, C. A.; Lorzing, G. R.; Bhattacharjee, R.; Caratzoulas, S.; Yap, G. P. A.; Bloch, E. D. Chem. Commun. 2020, 56, 9352-9355.

(57) “Synthesis and Characterization of Low-Nuclearity Lantern-Type Porous Coordination Cages” Taggart, G. A.; Lorzing, G. R.; Dworzak, M. R.; Yap, G. P. A.; Bloch, E. D. Chem. Commun. 2020, 56, 8924-8927.
Invited Contribution-Emerging Investigators 2020

(56) “Ligand-Based Phase Control in Porous Zirconium Coordination Cages” Gosselin, A. J.; Decker, G. E.; McNichols, B. W.; Baumann, J. E.; Yap, G. P. A.; Sellinger, A.; Bloch, E. D. Chem. Mater. 2020, 32, 5872-5878.

(55) “Permanently Microporous Metal-Organic Polyhedra” Gosselin, A. J.; Rowland, C. A.; Bloch, E. D. Chem. Rev. 2020, 120, 8987-9014.
Invited Contribution-Thematic Issue 2020 – Porous Framework Chemistry

(54) “Novel Syntheses of Carbazole-3,6-Dicarboxylate Ligands and Their Utilization for Porous Coordination Cages” Rowland, C. A.; Yap, G. P. A.; Bloch, E. D. Dalton Trans. 2020, 49, 16340-16347.
Invited Contribution-Special Issue: New Talent: Americas

(53) “Tuning the Porosity, Solubility, and Gas Storage Properties of Cuboctahedral Coordination Cages via Amide or Ester Functionalization” Taggart, G. A.; Antonio, A. M.; Lorzing, G. R.; Yap, G. P. A.; Bloch, E. D. ACS Appl. Mater. Interfaces 2020, 12, 24913-24919.

(52) “A Charged Coordination Cage Based Porous Salt” Gosselin, A. J.; Decker, G. E.; Antonio, A. M.; Lorzing, G. R.; Yap, G. P. A.; Bloch, E. D. J. Am. Chem. Soc. 2020, 142, 9594-9598.
(51) “Structure and Redox Tuning of Gas Adsorption Properties in Calixarene-Supported Fe(II)-Based Porous Cages” Deegan, M. M.; Ahmed, T. S.; Yap, G. P. A.; Bloch, E. D. Chem. Sci. 202011, 5273-5279.

(50) “Atomically Precise Crystalline Materials Based on Kinetically Inert Metal Ions by Reticular Mechanopolymerization” Gao, W.-Y.; Sur, A.; Wang, C.-H.; Lorzing, G. R.; Antonio, A. M.; Taggart, G. A.; Ezazi, A. A.; Bhuvanesh, N.; Bloch, E. D.; Powers, D. C. Angew. Chem. Int. Ed. 202059, 10878-10883.

(49) “MOF-Mimetic Molecules: Carboxylate-Based Supramolecular Complexes as Molecular Metal-Organic Framework Analogues” Decker, G. E.; Lorzing, G. R.; Deegan, M. M.; Bloch, E. D. J. Mater. Chem. A 20208, 4217-4229.
Invited Contribution.

(48) “Neutron Diffraction Structural Study of CO2 Binding in Mixed-Metal CPM-200 Metal-Organic Frameworks” Campanella, A. J.; Trump, B. A.; Gosselin, A. J.; Bloch, E. D.; Brown, C. M. Chem. Commun. 2020, 56, 2574-2577.(47) “Design and Synthesis of Capped-Paddlewheel-Based Porous Coordination Cages” Lorzing, G. R.; Gosselin, A. J.; Lindner, B. S.; Bhattacharjee, R.; Yap, G. P. A.; Caratzoulas, S.; Bloch, E. D. Chem. Commun. 2019, 55, 9527-9530.

(46) “Understanding Gas Storage in Cuboctahedral Porous Coordination Cages” Lorzing, G. R.; Gosselin, A. J.; Trump, B. A.; York, A. H. P.; Sturluson, A.; Rowland, C. A.; Yap, G. P. A.; Brown, C. M.; Simon, C. M. Bloch, E. D. J. Am. Chem. Soc. 2019, 141, 12128-12138.

(45) “Electrochemically-Mediated Syntheses of Titanium(III)-Based Metal-Organic Frameworks” Antonio, A. M.; Rosenthal, J.; Bloch, E. D. J. Am. Chem. Soc. 2019, 141, 11383-11387.

(44) “Controlling Size, Defectiveness, and Fluorescence in Nanoparticle UiO-66 Through Water and Ligand Modulation” Decker, G. E.; Stillman, Z.; Attia, L.; Fromen, C. A.; Bloch, E. D. Chem. Mater. 2019, 31, 4831-4839.

(43) “High-Pressure Methane Storage and Selective Gas Adsorption in a Cyclohexane-Functionalized Porous Organic Cage” Charles, C. D.; Bloch, E. D. Supramolecular Chemistry 2019, 31, 508-513.
Invited Contribution-Special Issue: Emerging Supramolecular Chemists in the United States.

(42) “Mechanochemical Synthesis of Two-Dimensional Metal-Organic Frameworks” Barreda, O.; Lorzing, G. R.; Bloch, E. D. Powder Diffraction 201934, 119-123.
Invited Contribution-Special Issue: Metal-Organic Frameworks.

(41) “Methane Storage in Paddlewheel-Based Porous Coordination Cages” Rowland, C. A.; Lorzing, G. R.; Gosselin, A. J.; Trump, B. A.; Yap, G. P. A.; Brown, C. M.; Bloch, E. D. J. Am. Chem. Soc. 2018, 140, 11153-11157.

(40) “Gas Adsorption in an Isostructural Series of Pillared Coordination Cages” Gosselin, A. J.; Lorzing, G. R.; Trump, B. A.; Brown, C. M.; Bloch, E. D. Chem. Commun. 2018, 54, 6392-6395.

(39) “Mechanochemical Synthesis of Porous Molecular Assemblies” Barreda, O.; Taggart, G. A.; Rowland, C. A.; Yap, G. P. A.; Bloch, E. D. Chem. Mater. 2018, 30, 3975-3978.

(38) “Design and Synthesis of Porous Nickel(II) and Cobalt (II) Cages” Gosselin, A. J.; Rowland, C. A.; Balto, K. P.; Yap, G. P. A.; Bloch, E. D. Inorg. Chem. 2018, 57, 11847-11850.

(37) “Ligand-Based Phase Control in Porous Molecular Assemblies” Barreda, O.; Bannwart, G.; Yap, G. P. A.; Bloch, E. D. ACS Appl. Mater. Interfaces 201810, 11420-11424.

(36) “Selective Gas Adsorption in Highly Porous Chromium(II)-Based Metal-Organic Polyhedra” Lorzing, G. R.; Trump, B. A.; Brown, C. M.; Bloch, E. D. Chem. Mater. 201729, 8583-8587.

 

Prior to University of Delaware:
(35) “Oxygen Activation at a Dicobalt Centre of a Dipyridylethane Naphthyridine Complex” Brodsky, C. N.; Passard, G.; Ullman, A. M.; Jaramillo, D. E.; Bloch, E. D.; Huynh, M.; Costentin, C.; Nocera, D. G. Dalton Trans. 2018, 47, 11903-11908.
(34) “An Experimental and Computational Study of CO2 Adsorption in the Sodalite-Type M-BTT (M = Cr, Mn Fe, Cu) Metal-Organic Frameworks Featuring Open Metal Sites” Asgari, M.; Jawahery, S.; Bloch, E. D.; Hudson, M. R.; Flacau, R.; Vlaisavljevich, B.; Boyd, P. G.; Smit, B.; Long, J. R.; Brown, C. M.; Queen, W. L. Chem. Sci. 2018, 9, 4579-4588.
(33) “Structurally Characterized Terminal Manganese(IV) Oxo Tris(alkoxide) Complex” Halbach, R. L.; Gygi, D.; Bloch, E. D.; Anderson, B. L.; Nocera, D. G. Chem. Sci. 2018, 9, 4524-4528.
(32) “Separation of Xylene Isomers through Multiple Metal Site Interactions in Metal-Organic Frameworks” Gonzalez, M. I.; Kapelewski, M. T.; Bloch, E. D.; Milner, P. J.; Reed, D. A.; Hudson, M. R.; Mason, J. A.; Barin, G.; Brown, C. M.; Long, J. R. J. Am. Chem. Soc. 2018140, 3412-3422.
(31) “Structural Characterization of Framework-Gas Interactions in the Metal-Organic Framework Co2(dobdc) by in situ Single-Crystal X-ray Diffraction” Gonzalez, M. I.; Mason, J. A.; Bloch, E. D.; Teat, S. J.; Gagnon, K. J.; Morrison, G. Y.; Queen, W. L.; Long, J. R.  Chem. Sci. 20178, 4387-4398.
(30) “Metal Insertion in a Methylamine-Functionalized Zirconium Metal-Organic Framework for Enhanced Carbon Dioxide Capture” Gomora-Figueroa, A. P.; Mason, J. A.; Gonzalez, M. I.; Bloch, E. D.; Meihaus, K. R. Inorg. Chem201756, 4308-4316.
(29) “Hydrogen Storage and Selective, Reversible O2 Adsorption in a Metal-Organic Framework with Open Chromium(II) Sites” Bloch, E. D.; Queen, W. L.; Hudson, M. R.; Mason, J. A.; Xiao, D. J.; Murray, L. J.; Flacau, R.; Brown, C. M.; Long, J. R. Angew. Chem. Int. Ed. 201655, 8605-8609.
(28) “Hydrogen Storage in the Expanded Pore Metal-Organic Frameworks M2(dobpdc) (M = Mg, Mn, Fe, Co, Ni, Zn)” Gygi, D.; Bloch, E. D.; Mason, J. A.; Hudson, M. R.; Gonzalez, M. I.; Siegelman, R. L.; Queen, W. L.; Brown, C. M.; Long, J. R. Chem. Mater. 2016, 28, 1128-1138.
(27) “Electronic Structure of Copper Corroles” Lemon, C. M.; Huynh, M.; Maher, A. G.; Anderson, B. L.; Bloch, E. D.; Powers, D. C.; Nocera, D. G. Angew. Chem. Int. Ed. 2016, 55, 2176-2180.
(26) “Influence of Solvent-like Side Chains on the Adsorption of Light Hydrocarbons in Metal-Organic Frameworks” Schneemann, A.; Bloch, E. D.; Henke, S.; Llewellyn, P. L.; Long, J. R.; Fischer, R. A. Chem. Eur. J. 2015, 21, 18764-18769.
(25) “Critical Factors Driving the High Volumetric Uptake of Methane in Cu3(btc)2“Hulvey, Z.; Vlaisavljevich, B.; Mason, J. A.; Tsivion, E.; Dougherty, T. P.; Bloch, E. D.; Head-Gordon, M.; Smit, B.; Long, J. R.; Brown, C. B. J. Am. Chem. Soc. 2015, 137, 10816-10825.
(24) “Carbohydrate-Mediated Purification of Petrochemicals” Holcroft, J. M.; Hartlieb, K. J.; Moghadam, P. Z.; Bell, J. G.; Barin, G.; Ferris, D. P.; Bloch, E. D.; Algaradah, M. M.; Nassar, M. S.; Botros, Y. Y.; Thomas, K. M.; Long, J. R.; Snurr, R. Q.; Stoddart, J. F. J. Am. Chem. Soc. 2015, 137, 5706-5719.
(23) “Gradual Release of Strongly-Bound Nitric Oxide from Fe2(NO)2(dobdc)” Bloch, E. D.; Queen, W. L.; Chavan, S.; Wheatley, P. S.; Zadrozny, J. M.; Morris, R.; Brown, C. M.; Lamberti, C.; Bordiga, S.; Long, J. R. J. Am. Chem. Soc. 2015, 137, 3466-3469.
(22) “Single-Crystal-to-Single-Crystal Metallation of a Metal-Organic Framework: A Route Towards Structurally Well-Defined Heterogeneous Catalysts” Gonzalez, M. I.; Bloch, E. D.; Teat, S. J.; Long, J. R. Inorg. Chem. 2015, 54, 2995-3005.
(21) “Cooperative Insertion of CO2 in Diamine-Appended Metal-Organic Frameworks” McDonald, T. M.; Mason, J. A.; Kong, X.; Bloch, E. D.; Gygi, D.; Dani, A.; Crocellà, V.; Giordanino, F.; Odoh, S. O.; Dridell, W.; Vlaisavljevich, B.; Dzubak, A. L.; Poloni, R.; Schnell, S. K.; Planas, N.; Lee, K.; Pascal, T.; Wan, L. F.; Prendergast, D.; Neaton, J. B.; Smit, B.; Kortright, J. B.; Gagliardi, L.; Bordiga, S.; Reimer, J. A.; Long, J. R. Nature 2015, 519, 303-308.
(20) “Rapidly Assessing the Activation Conditions and Porosity of Metal-Organic Frameworks Using Thermogravimetric Analysis” McDonald, T. M.; Bloch, E. D.; Long, J. R. Chem. Commun. 2015, 51, 4985-4988.
(19) “Counteranion Effects on the Catalytic Activity of Copper Salts Immobilized on the Bipyridine-Functionalized Metal-Organic Framework MOF-253” Valvekens, P.; Bloch, E. D.; Long, J. R.; Ameloot, R.; De Vos, D. E. Cat. Today 2015, 246, 55-59.
(18) “NMR Relaxation and Exchange in Metal-Organic Frameworks for Surface Area Screening” Chen, J. J.; Mason, J. A.; Bloch, E. D.; Gygi, D.; Long, J. R.; Reimer, J. A. Microporous Mesoporous Mater. 2015, 205, 65-69.
(17) “Comprehensive Study of Carbon Dioxide Adsorption in the Metal-Organic Frameworks M2(dobdc) (M = Mg, Mn, Fe, Co, Ni, Cu, Zn)” Queen, W. L.; Bloch, E. D.; Hudson, M. R.; Mason, J. M.; Gonzalez, M. I.; Lee, J.; Gygi, D.; Howe, J. D.; Lee, K.; Darwish, T.; James, M.; Peterson, V. K.; Teat, S. J.; Smit, B.; Neaton, J. R.; Long, J. R.; Brown, C. M. Chem. Sci. 2014, 5, 4569-4581.
(16) “Reversible CO Binding Enables Tunable CO/H2 and CO/N2 Separations in Metal-Organic Frameworks with Exposed Divalent Metal Cations” Bloch, E. D.; Hudson, M. R.; Mason, J. A.; Chavan, S.; Crocellà, V.; Howe, J. D.; Lee, K.; Dzubak, A. L.; Queen, W. L.; Zadrozny, J. M.; Geier, S. J.; Lin, L. –C.; Gagliardi, L.; Smit, B.; Neaton, J. B.; Bordiga, S.; Brown, C. M.; Long, J. R. J. Am. Chem. Soc. 2014, 136, 10752-10761.
(15) “CO2 Adsorption in Fe2(dobdc): A Classical Force Field Parameterized from Quantum Mechanical Calculations” Borycz, J.; Lin, L. -C.; Bloch, E. D.; Kim, J.; Dzubak, A. L.; Maurice, R.; Semrouni, D.; Lee, K.; Smit, B.; Gagliardi, L. J. Phys. Chem. C 2014, 118, 12230-12240.
(14) “Oxidation of Ethane to Ethanol by N2O in a Metal-Organic Framework with Coordinatively Unsaturated Iron(II) Sites” Xiao, D. J.; Bloch, E. D.; Mason, J. A.; Queen, W. L.; Hudson, M. R.; Planas, N.; Borycz, J.; Dzubak, A. L.; Verma, P.; Lee, K.; Bonino, F.; Crocellà, V.; Yano, J.; Bordiga, S.; Truhlar, T. G.; Gagliardi, L.; Brown, C. M.; Long, J. R. Nat. Chem. 2014, 6, 590-595.
(13) “Multifunctional, Defect-Engineered Metal-Organic Frameworks with Ruthenium Centers: Sorption and Catalytic Properties” Kozachuk, O.; Luz, I.; Llabrés i Xamena, F. X.; Noei, H.; Kauer, M.; Albada, H. B.; Bloch, E. D.; Marler, B.; Wang, Y.; Muhler, M.; Fischer, R. A. Angew. Chem. Int. Ed. 2014, 53, 7058.
(12) “Selective Propene Oligomerization with Nickel(II)-Based Metal-Organic Frameworks” Mlinar, A. N.; Keitz, B. K.; Gygi, D.; Bloch, E. D.; Long, J. R.; Bell, A. T. ACS Catal. 2014, 4, 717-721.
(11) “Design of a Metal-Organic Framework with Enhanced Back Bonding for the Separation of N2 and CH4” Lee, K.; Lin, L.-C.; Kim, J.; Isley, W. C.; Dzubak, A.; Verma, P.; Bloch, E. D.; Reed, D. A.; Long, J. R.; Neaton, J.; Smit, B.; Cramer, C. J.; Truhlar, D. G.; Gagliardi, L. J. Am. Chem. Soc. 2014, 136, 698-704.
(10) “Hydrocarbon Separations in Metal-Organic Frameworks” Herm, Z. R.; Bloch, E. D.; Long, J. R. Chem. Mater. 2014, 26, 323-338.
(9) “Highly Selective Quantum Sieving of D2 from H2 by a Metal-Organic Framework as Determined by Gas Manometry and Infrared Spectroscopy” FitzGerald, S. A.; Pierce, C. J.; Rowsell, J. L. C.; Bloch, E. D.; Mason, J. A. J. Am. Chem. Soc. 2013, 135, 9458-9464.
(8) “Selective Adsorption of Ethylene over Ethane and Propylene over Propane in the Metal-Organic Frameworks M2(dobdc) (M = Mg, Mn, Fe, Co, Ni, Zn)” Geier, S. J.; Mason, J. A.; Bloch, E. D.; Queen, W. L.; Hudson, M. R.; Brown, C. M.; Long, J. R. Chem. Sci. 2013, 4, 2054-2061.
(7) “Impact of Metal and Anion Substitutions on the Hydrogen Storage Properties of M-BTT Metal-Organic Frameworks” Sumida, K.; Stück, D.; Mino, L.; Chai, J. -D.; Bloch, E. D.; Zavorotynska, O.; Murray, L. J.; Dincă, M.; Chavan, S.; Bordiga, S.; Head-Gordon, M.; Long, J. R. J. Am. Chem. Soc. 2013, 135, 1083-1091.
(6) “Hydrocarbon Separations in a Metal-Organic Framework with Open Iron(II) Coordination Sites” Bloch, E. D.; Queen, W. L.; Krishna, R.; Zadrozny, J. M.; Brown C. M.; Long, J. R. Science 2012, 335, 1606-1610.
(5) “Hydrogen Adsorption in the Metal-Organic Frameworks Fe2(dobdc) and Fe2(O2)(dobdc)” Queen, W. L.; Bloch, E. D.; Brown, C. M.; Hudson, M. R.; Mason, J. A.; Murray, L. J.; Ramirez-Cuesta, A. J.; Peterson, V. K.; Long, J. R. Dalton Trans. 2012, 41, 4180-4187.
(4) “Acetylene Adsorption on CPO-27-M Metal-Organic Frameworks (M=Fe, Co, and Ni)” Chavan, S. M.; Shearer, G. C.; Bloch, E. D.; Bordiga, S. ChemPhysChem 2012, 13, 445-448.
(3) “Carbon Dioxide Capture in Metal-Organic Frameworks” Sumida, K.; Rogow, D. L.; Mason, J. A.; McDonald, T. M.; Bloch, E. D.; Herm, Z. R.; Bae, T.-H.; Long, J. R. Chem. Rev. 2012, 112, 724-781.
(2) “Selective Binding of O2 over N2 in a Redox-Active Metal-Organic Framework with Open Iron(II) Coordination Sites” Bloch, E. D.; Murray, L. M.; Queen, W. L.; Chavan, S.; Maximoff, S. N.; Bigi, J. P.; Krishna, R.; Peterson, V. K.; Grandjean, F.; Long, G. J.; Smit, B.; Bordiga, S.; Brown, C. M.; Long, J. R. J. Am. Chem. Soc. 2011, 133, 14814-14822.
(1) “Metal Insertion in a Microporous Metal-Organic Framework Lined with 2,2′-Bipyridine” Bloch, E. D.; Britt, D.; Doonan, C. J.; Uribe-Romo, F. J.; Furukawa, H.; Long, J. R.; Yaghi, O. M. J. Am. Chem. Soc. 2010, 132, 14382-14384.

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